Hohenheim scientists detect alarmingly high levels of pollutants in vitamin E supplements [21.05.19]
Chlorinated paraffins are increasingly environmentally relevant pollutants caused by humans. Several studies have already investigated chlorinated paraffins uptake through diet. Hohenheim scientists have now investigated the load of chlorinated paraffins for 25 food supplements. Six palm oil-containing vitamin E preparations showed alarmingly high concentrations of this pollutant. In order to put a stop to this pollution, regular monitoring of chlorinated paraffins could be considered.
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Publication
Sprengel, Jannik; Wieselmann, Sina; Kröpfl, Alexander; Vetter, Walter (2019): High amounts of chlorinated paraffins in oil-based vitamin E dietary supplements on the German market. In: Environment international 128, S. 438–445. DOI: 10.1016/j.envint.2019.04.065.
Abstract
Chlorinated paraffins (CPs) are a group of man-made pollutants of growing environmental concern. Short-chain chlorinated paraffins (SCCPs) were recently classified as persistent organic pollutants (POPs), while medium-chain chlorinated paraffins (MCCPs) are still unregulated. Foodstuff is a major pathway for the human CP intake, and the regular diet has been analyzed in several studies recently. However, dietary supplements (DS) had not been analyzed on CPs. Our goal was to investigate the occurrence of CPs in DS and to evaluate the possible threat for the consumers. DS (n = 25) made from plant or fish oils were selected on the German market with main emphasis on vitamin E products. The lipid components were removed by sulphuric acid treatment and silica gel column chromatography. CP quantification was performed via gas chromatography coupled to electron capture negative ion mass spectrometry. Six vitamin E preparations containing palm oil showed alarmingly high CP concentrations of >35 μg/g fat. Six other DS contained much lower CP amounts (<4 μg/g fat). If consumed as recommended, the mean daily intake of CPs (5.5 μg SCCPs + 38 μg MCCPs) via palm oil based DS surpassed that of the regular diet by a factor of 4 for SCCPs and 13 for MCCPs, exceeding the PCB intake via food by up to two orders of magnitude. Samples reached up to 26% of the TDI of MCCPs for an average European adult. Consequently, the P95 intake of those samples would amount to ~43 mg CPs per year. The CP contamination probably originated from raw material, as CPs were also found in palm oils and vitamin E concentrates made from palm oil. Our findings suggest that DS can contain high amounts of contaminants that compromise the purpose of the product and should be considered for regular CP monitoring.
